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61 The design and construction of transition metal supramolecular complexes with aminoacid-based Schiﬀ bases have also attracted great interest, because of their potential applications in many fields, like in magnetism, asymmetric 28 | Amino Acids, Pept. Proteins, 2014, 39, 21–67 . 1039/9781849739962-00021 View Online catalysis, luminescent probes, and biological functional materials. This versatility of the potential applications initiated the synthesis of two new ternary complexes [Cu2(L1)2(bpy)(EtOH)2] (H2L1 = b-Phe, N-[1-(2-hydroxyphenyl)propylidene], bpy = 4,40-bipyridine, EtOH = ethanol) and [CuL2(im)] (H2L2 = b-(2-chlorophenyl)alanine, N-[1-(2-hydroxyphenyl)propylidene], im = imidazole).