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By Maxim Ryadnov; Ferenc Hudecz

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M. Cergol and R. J. Payne, ChemBioChem, 2013, 14, 559. R. E. Thompson, B. Chan, L. Radom, K. A. Jolliffe and R. J. Payne, Angew. , Int. , 2013, 52, 9723. X. Guan, M. R. Drake and Z. Tan, Org. , 2013, 15, 6128. K. M. Cergol, R. E. Thompson, L. R. Malins, P. Turner and R. J. Payne, Org. , 2014, 16, 290. T. M. Hackeng, J. H. Griffin and P. E. Dawson, Proc. Natl. Acad. , 1999, 96, 10068. S. Shang, Z. Tan and S. J. Danishefsky, Proc. Natl. Acad. , 2011, 108, 5986. J. Li, S. Dong, S. D. Townsend, T. Dean, T.

Payne, Org. , 2012, 14, 3142. L. R. Malins, N. J. Mitchell and R. J. Payne, J. Pept. , 2014, 20, 64. F. Mende and O. Seitz, Angew. , Int. , 2011, 50, 1232. J. Brask, F. Albericio and K. J. Jensen, Org. , 2003, 5, 2951. P. Botti, M. Villain, S. Manganiello and H. Gaertner, Org. , 2004 6, 4861. H. Hojo, Y. Onuma, Y. Akimoto, Y. Nakahara and Y. , 2007, 48, 25. Y. Ohta, S. Itoh, A. Shigenaga, S. Shintaku, N. Fujii and A. Otaka, Org. , 2006, 8, 467. F. Nagaike, Y. Onuma, C. Kanazawa, H. Hojo, A. Ueki, Y.

61 The design and construction of transition metal supramolecular complexes with aminoacid-based Schiff bases have also attracted great interest, because of their potential applications in many fields, like in magnetism, asymmetric 28 | Amino Acids, Pept. Proteins, 2014, 39, 21–67 . 1039/9781849739962-00021 View Online catalysis, luminescent probes, and biological functional materials. This versatility of the potential applications initiated the synthesis of two new ternary complexes [Cu2(L1)2(bpy)(EtOH)2] (H2L1 = b-Phe, N-[1-(2-hydroxyphenyl)propylidene], bpy = 4,40-bipyridine, EtOH = ethanol) and [CuL2(im)] (H2L2 = b-(2-chlorophenyl)alanine, N-[1-(2-hydroxyphenyl)propylidene], im = imidazole).

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